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WHY
DO ATOMS COMBINE ?
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The
answer to this question is hidden in the electronic configurations
of the noble gases. It was found that noble gases namely
helium, neon, argon, krypton, xenon and radon did not react
with other elements to form compounds, i.e. they were non-reactive.
Earlier they were also called as inert gases. It was, thus,
thought that these noble gases lacked reactivity because
they had electronic arrangements which were quite stable.
When we write the electronic configurations of the noble
gases (see table 5.1 below), we find that except helium
all of them have 8 electrons in their outermost shell.
Electronic
configuration of Noble gases
|
Name
|
Symbol
|
Atomic
number
|
Electronic
configuration
|
No.
of electrons in the outermost shell
|
|
Helium
|
He
|
2
|
2
|
2
|
|
Neon
|
Ne
|
10
|
2,8
|
8
|
|
Argon
|
Ar
|
18
|
2,8,8
|
8
|
|
Krypton
|
Kr
|
36
|
2,8,18,8
|
8
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|
Xenon
|
Xe
|
54
|
2,8,18,18,8
|
8
|
|
Radon
|
Ra
|
86
|
2,8,18,32,18,8
|
8
|
Thus,
it was concluded that atoms having 8 electrons in their
outermost shell are very stable and they did not form compounds.
It was also observed that other atoms such as hydrogen,
sodium, chlorine etc. which do not have 8 electrons in their
outermost shell undergo chemical reactions. They can stabilize
by combining with each other and attaining the above configurations
of noble gasses, i.e. 8 electrons (or 2 electrons in case
of helium) in their outermost shells. Thus, atoms tend
to attain a configuration in which they have 8 electrons
in their outermost shells. This is called the octet
rule. The octet rule explains the chemical bonding in
many compounds.
Atoms are held together in compounds by the forces of attraction
which are called chemical bonds. The formation of
chemical bonds results in the lowering of energy, i.e. as
compared to the individual atoms the resulting compound
is lower in energy and hence is more stable. Thus stability
of the compound formed is an important factor in the formation
of chemical bonds. In rest of the lesson; you will study
about the nature of bonds present in various substances.
We would explain ionic bonding and covalent bonding in detail
while briefly touch upon the bonding in metals and hydrogen
bonding. Before you start learning about ionic bonding in
the next section, you can answer the following questions
to check your understanding.
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