In
the last section we discussed the nature of three important
types of substancesacids, bases and salts. They show
their typical properties in aqueous solutions. In this section
we shall learn about their behaviour in such solutions.
Electrolytes
and nonelectrolytes
An electrolyte is a substance that conducts electric
current through it in the molten state or through its solution.
The most familiar electrolytes are acids, bases, and salts,
which dissociate in their molten state when dissolved in
such solvents as water or alcohol. When common salt (sodium
chloride, NaCl) is dissolved in water, it forms an electrolytic
solution, dissociating into positive sodium ions (Na+)
and negative chloride ions (Cl-;).
A nonelectrolyte is a substance that does not
conduct electric current through it in the molten state
or through its solution. Nonelectrolytes consist of
molecules that bear no net electric charge and they do not
dissociate in their molten state or in their solutions.
Sugar dissolved in water maintains its molecular integrity
and does not dissociate and it is a nonelectrolyte.
Strong
and weak electrolytes
In the last section we learned that electrolytes dissociate
into ions in their solutions. Some electrolytes are completely
dissociated into ions. They are called strong electrolytes.
Sodium chloride, potassium hydroxide and hydrochloric acid
are strong electrolytes. On the other hand some other electrolytes
are dissociated only partially into ions. They are called
weak electrolytes. Acetic acid and ammonium hydroxide are
weak electrolytes.
Dissociation
of acids and bases in water
In the last section we learned that some electrolytes are
strong while others are weak. In this section we shall study
more about dissociation processes that occur in aqueous
solutions of acids and bases.