In
the last section, we have learnt how chemical reactions
have been classified into various types on the basis of
the nature of chemical change that occurs in them. In this
section we shall learn about some other features of chemical
reactions. These features have been discussed below.
Homogeneous-hetrogeneous
reacctions
Chemical
reactions can be classified on the basis of physical states
of reactants and products as homogeneous and heterogeneous
reactions.
a)
Homogeneous reactions
The
reactions in which all the reactants and products are present
in the same phase are called homogeneous reactions. Such
reactions can occur in gas phase or solution phase only.
A. Gas phase homogeneous reactions
These
are the reactions in which all reactants and products are
gases.
|
(
i ) H2(g)
|
+
|
Cl2(g)
|
>
|
2HCl(g)
|
|
hydrogen
|
|
chlorine
|
|
hydrogen
chloride
|
|
(
ii ) 2SO2(g)
|
+
|
O2(g)
|
>
|
2SO3(g)
|
|
sulphur
dioxide
|
|
oxygen
|
|
sulphur
trioxide
|
|
(iii)
N2(g)
|
+
|
3H2(g)
|
>
|
2NH3(g)
|
|
nitrogen
|
|
hydrogen
|
|
ammonia
|
B.Solution
phase homogeneous reactions
These
are the reactions in which all reactants and products are
present in a solution
|
(
i )
|
HCl(aq)
|
+
|
NaOH(aq)
|
>
|
NaCl(aq)
|
+
|
H2O(l)
|
|
|
hydrochloric
acid
|
|
sodium
hydroxide
|
|
sodium
chloride
|
|
water
|
|
(
ii )
|
CH3COOC2H5(l)
|
+
|
H2O(l)
|
>
|
CH3COOH(l)
|
+
|
C2H5OH(l)
|
b)
Hetrogeneous reactions
The
reactions in which reactants and products are present in
more than one phase are called heterogeneous reactions.
Such reactions involve at least one solid substance along
with one or more substances in solid, solution or gaseous
phase. The following are the examples of heterogeneous reactions.
|
(i)
CaCO3(s)
|
>
|
CaO(s)
|
+
|
CO2(g)
|
|
calcium carbonate
|
|
calcium
oxide
|
|
carbon
dioxide
|
|
(ii)
2Mg (s)
|
+
|
O2(g)
|
>
|
2MgO(s)
|
|
magnesium
|
|
oxygen
|
|
magnesium
oxide
|
|
(iii) BaCl2 (aq)
|
+
|
Na2SO4(aq)
|
>
|
BaSO4(s) |
+ |
2NaCl(aq) |
|
barium chloride
|
|
sodium
sulphate
|
|
barium
sulphate
|
|
sodium chloride |