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Nature of Chemical Reactions
 

In the last section, we have learnt how chemical reactions have been classified into various types on the basis of the nature of chemical change that occurs in them. In this section we shall learn about some other features of chemical reactions. These features have been discussed below.

Homogeneous-hetrogeneous reacctions

Chemical reactions can be classified on the basis of physical states of reactants and products as homogeneous and heterogeneous reactions.

a) Homogeneous reactions

The reactions in which all the reactants and products are present in the same phase are called homogeneous reactions. Such reactions can occur in gas phase or solution phase only.

A. Gas phase homogeneous reactions

These are the reactions in which all reactants and products are gases.

( i ) H2(g)
+
Cl2(g)
—>
2HCl(g)
hydrogen
chlorine
hydrogen chloride
( ii ) 2SO2(g)
+
O2(g)
—>
2SO3(g)
sulphur dioxide
oxygen
sulphur trioxide
(iii) N2(g)
+
3H2(g)
—>
2NH3(g)
nitrogen
hydrogen
ammonia

B.Solution phase homogeneous reactions

These are the reactions in which all reactants and products are present in a solution

( i )
HCl(aq)
+
NaOH(aq)
—>
NaCl(aq)
+
H2O(l)
hydrochloric acid
sodium hydroxide
sodium chloride
water
( ii )
CH3COOC2H5(l)
+
H2O(l)
—>
CH3COOH(l)
+
C2H5OH(l)

b) Hetrogeneous reactions

The reactions in which reactants and products are present in more than one phase are called heterogeneous reactions. Such reactions involve at least one solid substance along with one or more substances in solid, solution or gaseous phase. The following are the examples of heterogeneous reactions.

(i) CaCO3(s)
—>
CaO(s)
+
CO2(g)
calcium carbonate
calcium oxide
carbon dioxide
(ii) 2Mg (s)
+
O2(g)
—>
2MgO(s)
magnesium
oxygen
magnesium oxide
(iii) BaCl2 (aq)
+
Na2SO4(aq)
—>
BaSO4(s) + 2NaCl(aq)
barium chloride
sodium sulphate
barium sulphate
  sodium chloride
 
 
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